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Structures and magnetic properties of Mn and Co inorganic-organic frameworks with mixed linear dicarboxylate ligands

Abstract:

The structures and magnetic properties of two transition metal frameworks that feature a mixture of two linear dicarboxylate ligands are reported. Compounds 1, Mn 2(C 4H 4O 4)(C 6H 8O 4)(H 2O) 4· 2H 2O, and 2, Co 6(C 4H 4O 4) 4(C 6H 8O 4)(OH) 2(H 2O) 4·5H 2O, contain a mixture of succinate and adipate ligands but adopt significantly different structures. Compound 1 features layers of MnO 6 dimers, intra-connected by carboxylate groups, with neighbouring dimers connected to each other via the ...

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Publisher copy:
10.1039/c2ce05947a

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
CrystEngComm
Volume:
14
Issue:
8
Pages:
2711-2720
Publication date:
2012-04-21
DOI:
EISSN:
1466-8033
Source identifiers:
330196
Language:
English
Pubs id:
pubs:330196
UUID:
uuid:23a32d19-d0b9-4a6f-8913-7da4a8e03ceb
Local pid:
pubs:330196
Deposit date:
2013-11-16

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