The production of X-rays from electron transitions into K-shell vacancies (Kα,β) emission) is a well-known process in atomic physics and has been extensively studied as a plasma diagnostic in low-and mid-Z materials. However, X-ray spectra from near neutral high-Z ions are very complex, and their interpretation requires the use of state-of-the-art atomic calculations. In this experiment, the Titan laser system at Lawrence Livermore National Laboratory was used to deliver an approximately 350 ...