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Penta-fluoro-phenyl (3R,4R,5S)-5-{[(3R,4R,5S)-5-azido-methyl-3,4-dimeth-oxy-2,3,4,5-tetra-hydro-furan-3-carboxamido]-meth-yl}-3,4-dimeth-oxy-2,3,4,5-tetra-hydro-furan-3-carboxyl-ate.

Abstract:

The title compound, C(22)H(25)F(5)N(4)O(9), is a stable penta-fluoro-phenyl ester inter-mediate in the synthesis of novel homo-oligomeric structures containing branched carbon chains. The structure is epimeric to the previously characterized dimeric penta-fluoro-phenyl ester with stereochemistry (3R,4R,5R), which was synthesized using d-ribose as starting material. The crystal structure of the title mol-ecule removes any ambiguities arising from the relative stereochemistries of the six chira...

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Publication status:
Published

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Publisher copy:
10.1107/s1600536810038559

Authors


Simone, MI More by this author
Edwards, AA More by this author
Parker, SG More by this author
Tranter, GE More by this author
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Journal:
Acta crystallographica. Section E, Structure reports online
Volume:
66
Issue:
Pt 11
Pages:
o2699-o2700
Publication date:
2010
DOI:
EISSN:
1600-5368
ISSN:
1600-5368
URN:
uuid:2310cbaa-8e7f-4d15-9eec-327734dbce01
Source identifiers:
112622
Local pid:
pubs:112622
Language:
English

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