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Cold reactive collisions between laser-cooled ions and velocity-selected neutral molecules

Abstract:
We report a new experimental method to study reactive ion-molecule collisions at very low temperatures. A source of laser-cooled ions in a linear Paul trap has been combined with a quadrapole-guide velocity selector to investigate the reaction of Ca+ with CH3F at collision energies Ē_coll/ k_B ≥ 1 K with single-particle sensitivity. The technique represents a general approach to study reactive collisions between ions and polar molecules over a wide temperature range down to the cold regime.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1103/PhysRevLett.100.043203

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Chemistry Research Laboratory
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Chemistry Research Laboratory
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Chemistry Research Laboratory
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Chemistry Research Laboratory
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Chemistry Research Laboratory
Role:
Author
Engineering and Physical Sciences Research Council More from this funder
Publisher:
American Physical Society Publisher's website
Journal:
Physical Review Letters Journal website
Volume:
100
Issue:
4
Article number:
043203
Publication date:
2008-02-01
DOI:
EISSN:
1079-7114
ISSN:
0031-9007
Language:
English
Subjects:
UUID:
uuid:23022140-5b5b-464d-a9d7-ecd85adf2f6f
Local pid:
ora:2911
Deposit date:
2009-08-17

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