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Synthesis and reactions of β-diketiminate-supported complexes with Mg-Fe or Yb-Fe bonds.

Abstract:

Reaction of [M(NacNac)I(THF)]n (M = Mg, Ca or Yb; n = 1 or 2) with KFp gave Mg(NacNac)Fp(THF) (, Mg-Fe = 2.6326(4) Å) or [M(NacNac)(μ-Fp)(THF)]2 (M = Ca or Yb (10), no M-Fe bonds); reaction of with [YbFp2(THF)3]2 gave [{Yb(NacNac)(THF)}2(μ-YbFp4)] (Yb-Fe = 2.9758(5)-3.1702(5) Å) containing the first example of a lanthanide bound solely to four transition metals; reaction of with TolNCNTol gave Mg(NacNac){(NTol)2CFp} via the first net insertion of an unsaturated substrate into an alkaline eart...

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Publication status:
Published

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Publisher copy:
10.1039/c3cc41360h

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Chemical Communications
Volume:
49
Issue:
32
Pages:
3315-3317
Publication date:
2013-04-01
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Source identifiers:
390821
Language:
English
Pubs id:
pubs:390821
UUID:
uuid:2301f90e-0032-4f64-b72f-9e6aff08f0f1
Local pid:
pubs:390821
Deposit date:
2013-11-16

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