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New building blocks for efficient and highly diastereoselective polyol production - Synthesis and utility of (R ',R ',S,S) and (S ',S ',R,R)-2,3-butane diacetal protected butane tetrol derivatives

Abstract:
The efficient synthesis of aldehydes derived from 2,3butane diacetal protected butane tetrols (S1,S',R,R)-5 and (R',R',S,S)-6 and their utility in the controlled synthesis of polyhydroxylated materials through highly diastereoselective Lewis acid mediated addition reactions of allyltributylstannane and silyl enol ether nucleophiles is described.
Publication status:
Published

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Publisher copy:
10.1039/a902734c

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 More from this journal
Issue:
12
Pages:
1627-1629
Publication date:
1999-06-21
DOI:
EISSN:
1364-5463
ISSN:
0300-922X
Language:
English
Pubs id:
pubs:52108
UUID:
uuid:22c4e5af-972e-4644-ac01-96c65c280629
Local pid:
pubs:52108
Source identifiers:
52108
Deposit date:
2012-12-19

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