Journal article
A bis‐triazacyclononane tris‐pyridyl N9‐azacryptand “beer can” receptor for complexation of alkali metal and lead(II) cations
- Abstract:
- A new bis‐triazacyclononane tris‐pyridyl N9‐azacryptand ligand is prepared via a convenient one‐pot [2+3] condensation reaction between triazacyclononane and 2,6‐bis(bromomethyl) pyridine in the presence of M2CO3 (M=Li, Na, K). The proton, lithium, sodium, potassium and lead(II) complexes of the ligand are characterised in the solid state. Preliminary solution‐phase competition experiments indicate that the cryptand ligand preferentially binds lead(II) in the presence of sodium, calcium, potassium and zinc cations in methanol solution.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
-
-
(Preview, Accepted manuscript, 827.4KB, Terms of use)
-
- Publisher copy:
- 10.1002/chem.201801300
Authors
- Publisher:
- Wiley
- Journal:
- Chemistry - A European Journal More from this journal
- Volume:
- 24
- Issue:
- 41
- Pages:
- 10434-10442
- Place of publication:
- Germany
- Publication date:
- 2018-06-19
- Acceptance date:
- 2018-04-18
- DOI:
- EISSN:
-
1521-3765
- ISSN:
-
0947-6539
- Pmid:
-
29668116
- Language:
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English
- Keywords:
- Pubs id:
-
843428
- Local pid:
-
pubs:843428
- Deposit date:
-
2020-02-03
Terms of use
- Copyright holder:
- Wiley
- Copyright date:
- 2018
- Rights statement:
- © 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim.
- Notes:
- This is the accepted manuscript version of the article. The final version is available online from Wiley at: https://doi.org/10.1002/chem.201801300
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