Journal article
Bio‐inspired Domino oxa‐Michael/Diels–Alder/oxa‐Michael Dimerization of para‐Quinols
- Abstract:
- A bio‐inspired, pyrrolidine‐mediated, dimerization of para‐quinols has been developed. It represents one of the most complex, yet general, dimerization reactions ever disclosed, selectively forming four new bonds, four new rings, and eight new contiguous stereogenic centres. The para‐quinol starting materials are easily handled, bench‐stable compounds, accessed in just one step from aromatic feedstocks. The reaction can be scaled up to give grams of polycyclic material, primed for further elaboration.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
Actions
Authors
- Publisher:
- Wiley
- Journal:
- Angewandte Chemie International Edition More from this journal
- Volume:
- 57
- Issue:
- 21
- Pages:
- 6198-6202
- Publication date:
- 2018-04-25
- Acceptance date:
- 2018-04-10
- DOI:
- EISSN:
-
1521-3773
- ISSN:
-
1433-7851
- Pmid:
-
29637681
- Language:
-
English
- Keywords:
- Pubs id:
-
pubs:846235
- UUID:
-
uuid:22a63a66-7f48-4861-ac14-fd615ccb1eeb
- Local pid:
-
pubs:846235
- Source identifiers:
-
846235
- Deposit date:
-
2019-02-18
Terms of use
- Copyright holder:
- Wiley-VCH
- Copyright date:
- 2018
- Notes:
- © 2018 Wiley‐VCH Verlag GmbH and Co. KGaA, Weinheim.
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