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Tube electrode and electron spin resonance. First-order kinetics

Abstract:
Radical intermediates or products are generated on a tube electrode that is placed adjacent to an e.s.r. cavity. The radicals are carried by laminar flow from the electrode into the cavity. Theory is presented for the case where the radicals are decomposing by first-order kinetics in their passage to the cavity. Experiments carried out on nitrobenzene in the presence of IO4- and on p-phenylenediamine are shown to be in good agreement with the theory.
Publication status:
Published

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Publisher copy:
10.1039/f19807601391

Authors


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Institution:
University of Oxford
Role:
Author
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Institution:
University of Oxford
Role:
Author
More by this author
Institution:
University of Oxford
Role:
Author
Journal:
Journal of the Chemical Society, Faraday Transactions 1 More from this journal
Volume:
76
Issue:
0
Pages:
1391-1401
Publication date:
1980-01-01
DOI:
ISSN:
0300-9599
Language:
English
UUID:
uuid:22909a08-84b0-46ca-bddc-2716e3cedfbd
Local pid:
pubs:41910
Source identifiers:
41910
Deposit date:
2012-12-19

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