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Synthesis and characterisation of complexes of Group 13 metal amidinate heterocycles with the CpFe(CO)2 fragment.

Abstract:

The first examples of complexes between a 4-membered amidinato-Group 13 metal(III) heterocycle and a transition metal fragment are formed in salt elimination reactions between Na[CpFe(CO)2] and [MX2(amid)], M=Al, Ga or In; X=Cl or Br; amid-=[(RN)2CBut]-; R=Pri or cyclohexyl (Cy). The formed complexes, [CpFe(CO)2M(X)(amid)] (4 examples) have been crystallographically characterised and subject to halide abstraction reactions. In one case, the cationic complex, [CpFe(CO)2Ga(OEt2){(CyN)2CBut}][BA...

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Publication status:
Published

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Publisher copy:
10.1039/b611758a

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Dalton transactions (Cambridge, England : 2003) More from this journal
Issue:
45
Pages:
5357-5361
Publication date:
2006-12-01
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
Language:
English
Pubs id:
pubs:46046
UUID:
uuid:22231ab6-a4e9-4edb-9fed-a86ef00f108d
Local pid:
pubs:46046
Source identifiers:
46046
Deposit date:
2012-12-19

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