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Asymmetric synthesis of (2S,3S)- and (2R,3S)-2,3-diaminobutanoic acids, non-protein amino-acid diastereomers found in a number of peptide antibiotics

Abstract:
(2S,3S)- and (2R,3S)-2,3-diaminobutanoic acids (DABA) are uncommon, naturally occurring amino acid diastereomers found as components of a number of peptide antibiotics. These 2,3-diamino acids have been synthesised by direct and indirect routes, with addition of a chiral lithium amide to tert-butyl crotonate as a key step.
Publication status:
Published

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Publisher copy:
10.1055/s-1996-5556

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Hedgecock, CJR More by this author
Journal:
SYNLETT
Volume:
1996
Issue:
7
Pages:
621-and
Publication date:
1996-07-05
DOI:
EISSN:
1437-2096
ISSN:
0936-5214
URN:
uuid:220d7bc9-28ee-4273-a588-397ecc39cc21
Source identifiers:
110842
Local pid:
pubs:110842

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