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Fluoride binding and crystal-field analysis of lanthanide complexes of tetrapicolyl-appended cyclen

Abstract:

Lanthanide complexes of tetrapicolyl cyclen display remarkably high affinities for fluoride (log K ~ 5) in water, and are shown to form 1:1 complexes. The behaviour of these systems can be rationalised by changes to the magnitude of the crystal field parameter, B02. However, such changes are not invariably accompanied by a change in sign of this parameter: for early lanthanides the N8 donor set with a coordinated axial water molecule ensures that the magnetic anisotropy has the opposite sense...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1002/chem.201601170

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More from this funder
Name:
European Research Council
Grant:
267426
Publisher:
Wiley
Journal:
Chemistry: A European Journal More from this journal
Volume:
22
Issue:
26
Pages:
8929–8936
Publication date:
2016-01-01
Acceptance date:
2016-04-06
DOI:
ISSN:
1521-3765
Keywords:
Pubs id:
pubs:618184
UUID:
uuid:21de5413-f536-4408-ac0a-f54c379b6537
Local pid:
pubs:618184
Source identifiers:
618184
Deposit date:
2016-04-28

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