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Thesis

Exploring the reactivity patterns of cationic and neutral rhodium bis-phosphine species with amine-boranes

Abstract:

This thesis details the synthesis of novel Rh(I) and Rh(III) bis-phosphine fragments, and their use, along with other known rhodium species, to investigate the reactivity of amine-boranes, with a particular focus on the dehydrocoupling of the secondary amine-borane H3B.NMe2H (DMAB).

Chapter 2 utilises the new mixed phosphine, PtBuiBu2, to investigate the role of the phosphine with regard to the corresponding low-coordinate organometallic species isolated. Their coordination and reac...

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Institution:
University of Oxford
Oxford college:
University College
Department:
Mathematical,Physical & Life Sciences Division - Chemistry - Inorganic Chemistry Laboratory
Role:
Author

Contributors

Role:
Supervisor
Publication date:
2013
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
Oxford University, UK
URN:
uuid:21b883f1-9ffd-4589-ad82-1243b988af91
Local pid:
ora:7044

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