Thesis icon

Thesis

Exploring the reactivity patterns of cationic and neutral rhodium bis-phosphine species with amine-boranes

Abstract:

This thesis details the synthesis of novel Rh(I) and Rh(III) bis-phosphine fragments, and their use, along with other known rhodium species, to investigate the reactivity of amine-boranes, with a particular focus on the dehydrocoupling of the secondary amine-borane H3B.NMe2H (DMAB).

Chapter 2 utilises the new mixed phosphine, PtBuiBu2, to investigate the role of the phosphine with regard to the corresponding low-coordinate organometallic species isolated. Their coordination and reac...

Expand abstract

Actions


Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Oxford college:
University College
Role:
Author
More by this author
Division:
MPLS
Department:
Chemistry
Role:
Author

Contributors

Division:
MPLS
Department:
Chemistry
Role:
Supervisor
Publication date:
2013
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
Oxford University, UK
Language:
English
Keywords:
Subjects:
UUID:
uuid:21b883f1-9ffd-4589-ad82-1243b988af91
Local pid:
ora:7044
Deposit date:
2013-07-18

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP