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DOUBLE CHANNEL ELECTRODES AND THE MEASUREMENT OF HETEROGENEOUS REACTION-RATES AT THE SOLID LIQUID INTERFACE

Abstract:

The theory of collection efficiency measurements (under steady-state conditions) at double channel electrodes is extended to include the case where the species generated at the upstream electrode undergoes a heterogeneous reaction on the surface of the gap between the two electrodes. The problem is treated numerically using the Backwards Implicit method, which allows the collection efficiency to be related to the corresponding value of the rate constant for the heterogeneous process for chose...

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Publication status:
Published

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Publisher copy:
10.1007/BF01022266
Publisher:
Kluwer Academic Publishers
Journal:
JOURNAL OF APPLIED ELECTROCHEMISTRY More from this journal
Volume:
18
Issue:
4
Pages:
657-665
Publication date:
1988-07-01
DOI:
EISSN:
1572-8838
ISSN:
0021-891X
Language:
English
UUID:
uuid:2138d03b-80ae-4928-8938-50d8b161707e
Local pid:
pubs:43013
Source identifiers:
43013
Deposit date:
2012-12-19

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