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Reactivity studies of group 15 Zintl ions towards homoleptic post-transition metal organometallics: a 'bottom-up' approach to bimetallic molecular clusters.

Abstract:

Reactions between ethylenediamine (en) solutions of the intermetallic Zintl phases K(3)E(7) (E = P, As) and a series of homoleptic post-transition metal organometallics such as Cu(5)(Mes)(5), M(C(6)H(5))(2) (M = Zn, Cd) and In(C(6)H(5))(3) have yielded a family of novel bimetallic cluster anions. These new species were isolated as [K(2, 2,2-crypt)](+) salts in [K(2,2,2-crypt)](4)Cu(2)E(14) (E = P (1), As (2)), [K(2,2,2-crypt)](4)ZnE(14) (E = P (3), As (4)), [K(2,2,2-crypt)](4)CdP(14) x 6py (5...

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Publication status:
Published

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Publisher copy:
10.1039/b911544g

Authors


Denning, MS More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Journal:
Dalton transactions (Cambridge, England : 2003)
Volume:
39
Issue:
2
Pages:
426-436
Publication date:
2010-01-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:20a145af-9aca-49b7-ba0e-982db22ab39e
Source identifiers:
35028
Local pid:
pubs:35028
Language:
English

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