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A direct measurement of the O(D-1) quantum yields from the photodissociation of ozone between 300 and 328 nm

Abstract:

The relative quantum yields of O(1D) produced in the photolysis of ozone at 298 K between 300 and 328 nm have been measured directly by resonance-enhanced multiple photon ionisation of the fragment. Clear indications are seen of a tail in the quantum yield extending to the long-wavelength limit of the experiments. Comparisons with previous studies are made to assess the importance of the photolysis of vibrationally excited molecules and spin-forbidden dissociation at wavelengths beyond the 31...

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Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Martin, SE More by this author
deMoira, JCP More by this author
Journal:
CHEMICAL PHYSICS LETTERS
Volume:
264
Issue:
5
Pages:
531-538
Publication date:
1997-01-17
DOI:
ISSN:
0009-2614
URN:
uuid:2072e712-d50e-41d4-8dbc-72a6c7897b6e
Source identifiers:
45487
Local pid:
pubs:45487
Language:
English

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