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Photolysis wavelength dependence of the translational anisotropy and the angular momentum polarization of O2(a 1Deltag) formed from the UV photodissociation of O3.

Abstract:

The translational anisotropy and angular momentum polarization of the O(2)(a (1)Delta(g),v = 0;J = 15-27) molecular photofragment produced from the UV photodissociation of O(3) in the range from 270 to 300 nm have been determined using resonance-enhanced multiphoton ionization in conjunction with time-of-flight mass spectrometry. At the shortest photolysis wavelengths used, the fragments exhibit the anisotropic vector correlations expected from a prompt dissociation via the (1)B(2)

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Publication status:
Published

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Publisher copy:
10.1063/1.1944719

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
Journal of chemical physics More from this journal
Volume:
122
Issue:
24
Pages:
244321
Publication date:
2005-06-01
DOI:
EISSN:
1089-7690
ISSN:
0021-9606
Language:
English
Pubs id:
pubs:33178
UUID:
uuid:1f674156-02e5-4b27-854e-0fe36e6e6d36
Local pid:
pubs:33178
Source identifiers:
33178
Deposit date:
2012-12-19

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