- Abstract:
-
Rapid, efficient methods have been developed to prepare phenols from the oxidation of arylhydrosilanes. The effects of arene substituents and fluoride promoters on this process show that while electron-deficient arenes can undergo direct oxidation from the hydrosilane, electron-rich aromatics benefit from silane activation via oxidation to the methoxysilane using homogeneous or heterogeneous transition metal catalysis. The combination of these two oxidations into a streamlined flow procedure ...
Expand abstract - Publisher copy:
- 10.1021/jo301363h
-
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- Journal:
- The Journal of organic chemistry
- Volume:
- 77
- Issue:
- 16
- Pages:
- 7052-7060
- Publication date:
- 2012-08-05
- DOI:
- EISSN:
-
1520-6904
- ISSN:
-
0022-3263
- URN:
-
uuid:1f6586e8-5d2c-485e-bfa2-e11b2f5dcb39
- Source identifiers:
-
345641
- Local pid:
- pubs:345641
- Language:
- English
- Keywords:
- Copyright date:
- 2012
Journal article
Synthesis of phenols via fluoride-free oxidation of arylsilanes and arylmethoxysilanes.
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