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Boron

Abstract:

Molecular wheels of eight- and nine-atom boron clusters have been observed by photoelectron spectroscopy and their structures confirmed by DFT calculations 1. The first cationic terminal borylene, containing a Fe=B double bond, [Cp*Fe(CO) 2-(Bmesityl)][BAr f4] has been synthesised. DFT calculations support a bonding model in which boron engages in π-bonding to both [Cp*Fe(CO) 2] ...

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Publisher copy:
10.1039/b311777b

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Annual Reports on the Progress of Chemistry - Section A
Volume:
100
Pages:
35-53
Publication date:
2004-01-01
DOI:
ISSN:
0260-1818
Source identifiers:
330966
Language:
English
Pubs id:
pubs:330966
UUID:
uuid:1f320967-f90d-481a-a35c-97ac8e26e799
Local pid:
pubs:330966
Deposit date:
2012-12-19

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