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Switching transition states with changing electrode potential: Zn(II)/Zn electrodeposition on glassy carbon in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid

Abstract:

The mechanisms for the electrodeposition and stripping of Zn 2+|Zn in the N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid are investigated via cyclic voltammetry. Analysis showed that the deposition of Zn onto a bulk Zn surface occurred via a two-electron process, with the first electron transfer being rate determining. The electrodissolution was found to occur via a potentialdependent mechanism with the first electron transfer being rate determining near the form...

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Publication status:
Published

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Publisher copy:
10.1007/s10008-012-1731-6

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
JOURNAL OF SOLID STATE ELECTROCHEMISTRY More from this journal
Volume:
16
Issue:
7
Pages:
2329-2333
Publication date:
2012-07-01
DOI:
EISSN:
1433-0768
ISSN:
1432-8488
Language:
English
Keywords:
UUID:
uuid:1efa8ac3-3488-4b41-808b-bab83f0a1e35
Local pid:
pubs:342655
Source identifiers:
342655
Deposit date:
2012-12-19

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