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Aspects of organophosphorus chemistry

Abstract:

Chapter 1 This chapter is concerned with some reactions of diphenylvinylphosphine oxide (1). Phosphine oxfide (1) is known to undergo nucleophilic additions analogous to the Michael reaction. Triphenylvinylphosphonium bromide also undergoes a number of nucleophilic additions, including the Schweizer reaction. Thus, Triphenylvinylphosphonium bromide, upon treatment with the sodium salts of benzoin or salicylaldehyde, yields 2,3-diphenyl 2,5-dihydrofuran and 3,4-chromene, respectively. An a...

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Department:
University of Oxford
Role:
Author
Type of award:
DPhil
Level of award:
Doctoral
Awarding institution:
University of Oxford
UUID:
uuid:1ed07a5e-e79d-494c-9468-33f7a97af44c
Local pid:
polonsky:8:12
Source identifiers:
601870455
Deposit date:
2017-10-05

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