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Mechanistic studies of AFM probe-driven Suzuki and Heck molecular coupling.

Abstract:

The initiation and high resolution control of surface confined chemical reactions would be both beneficial for nanofabrication and fundamentally interesting. In this work, mechanistic aspects of spatially confined Suzuki and Heck 'catalytic nanolithography' are investigated by varying the experimental parameters and noting their effects on apparent reactivity and lithographic yield. A variety of molecular couplings can be driven by the activated scanning probe with linewidths ultimately limit...

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Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
Nanotechnology
Volume:
21
Issue:
26
Pages:
265302
Publication date:
2010-07-05
DOI:
EISSN:
1361-6528
ISSN:
0957-4484
URN:
uuid:1e854b7c-f878-4641-9377-d06eb5d198b6
Source identifiers:
60469
Local pid:
pubs:60469
Language:
English

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