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VIBRATIONAL PREDISSOCIATION IN D2HF

Abstract:

Calculations are presented of linewidths for the vibrational predissociation of D2 HF induced by excitation of the HF stretching vibration in the weakly bound molecule. A potential energy surface based on ab initio computations with the correct leading multipole terms has been used. The vibrational predissociation linewidths are obtained from accurate close-coupling computations of scattering resonances for the D2 + HF collision. The calculated linewidths are in excellent agreement with those...

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Publication status:
Published

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Publisher copy:
10.1063/1.462423

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Journal:
JOURNAL OF CHEMICAL PHYSICS
Volume:
96
Issue:
1
Pages:
90-97
Publication date:
1992
DOI:
ISSN:
0021-9606
URN:
uuid:1e621f6e-e3f2-49c0-9804-a642e596b1c6
Source identifiers:
53028
Local pid:
pubs:53028
Language:
English

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