Journal article
Intramolecular N center dot center dot center dot E interactions in N-functionalised alkyl complexes R ' ECl2 (E = P, As, Sb; R=6-Me-2-Pyr(SiMe3)(2)C-)
- Abstract:
-
The metathetical exchange reactions of R′Li·Et2O [R′ = 6-Me-2-Pyr(SiMe3)2C-] with ECl3 (E = P, As, Sb) give the neutral E(III) complexes, R′ECl2. All complexes have been crystallographically characterised and exhibit extremely short intramolecular N⋯E dative bonds, with the phosphorus derivative exhibiting the shortest neutral N⋯P dative bond of 2.238(1) Å. Theoretical studies performed with approximate density functional theory successfully model the unusual structural features of compound R...
Expand abstract
- Publication status:
- Published
Actions
Access Document
- Publisher copy:
- 10.1016/S0022-328X(00)00374-0
Why is the content I wish to access not available via ORA?
Bibliographic data (the information relating to research outputs) and full-text items (e.g. articles, theses, reports, etc.) arrive in ORA from several different sources. Unfortunately we are not able to make available the full-text for every research output.
Please contact the ORA team (
) if you have queries regarding unavailable content OR if you are aware of a full-text copy we can make available.
) if you have queries regarding unavailable content OR if you are aware of a full-text copy we can make available.
Content may be unavailable for the following four reasons
-
Version unsuitable
-
We have not obtained a suitable full-text for a given research output. See this page for more information.
-
Recently completed
-
Sometimes content is held in ORA but is unavailable for a fixed period of time to comply with the policies and wishes of rights holders.
-
Permissions
-
All content made available in ORA should comply with relevant rights, such as copyright. See this page for more information.
-
Clearance
-
Some thesis volumes scanned as part of the digitisation scheme funded by Dr Leonard Polonsky are currently unavailable due to sensitive material or uncleared third-party copyright content. We are attempting to contact authors whose theses are affected.
Alternative access to the full-text
You may be able to access the full-text directly from the publisher's website using the 'Publisher Copy' link in the 'Links & Downloads' box from a research output's ORA record page. This method may require an institutional or individual subscription to the journal/resource.
Authors
Bibliographic Details
- Journal:
- JOURNAL OF ORGANOMETALLIC CHEMISTRY
- Volume:
- 607
- Issue:
- 1-2
- Pages:
- 213-221
- Publication date:
- 2000-08-11
- DOI:
- ISSN:
-
0022-328X
- Source identifiers:
-
50472
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:50472
- UUID:
-
uuid:1e013aff-7b5f-4209-9470-3c62c16c24ee
- Local pid:
- pubs:50472
- Deposit date:
- 2012-12-19
Terms of use
- Copyright date:
- 2000
If you are the owner of this record, you can report an update to it here: Report update to this record