Journal article
Harnessing NMR relaxation interference effects to characterise supramolecular assemblies.
- Abstract:
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Solution-state NMR spectroscopy remains the primary method for characterizing synthetic supramolecular assemblies. Yet, in their NMR spectra, relaxation interference effects can significantly alter peak intensities hindering interpretation. Here, we present a simple experiment for synthetic chemists to analyse this effect, allowing interpretion of these distorted spectra and validation of spectral assignments. We apply this experiment to synthetic porphyrin oligomers with molecular weights ap...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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Access Document
- Files:
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(Accepted manuscript, pdf, 2.3MB)
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- Publisher copy:
- 10.1039/c6cc02544g
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Authors
Funding
+ Biotechnology and Biological Sciences Research Council
More from this funder
Funding agency for:
Baldwin, A
Grant:
BB/J014346/1
Engineering and Physical Sciences Research Council
More from this funder
Bibliographic Details
- Publisher:
- Royal Society of Chemistry Publisher's website
- Journal:
- Chemical Communications Journal website
- Volume:
- 52
- Issue:
- 47
- Pages:
- 7450-7453
- Publication date:
- 2016-04-01
- Acceptance date:
- 2016-04-15
- DOI:
- ISSN:
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1364-548X and 1359-7345
- Pmid:
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27122082
- Source identifiers:
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617739
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:617739
- UUID:
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uuid:1dd7e872-ff50-4e27-bd90-b3bf62600ad9
- Local pid:
- pubs:617739
- Deposit date:
- 2016-12-05
Terms of use
- Copyright holder:
- Royal Society of Chemistry
- Copyright date:
- 2016
- Notes:
- © Royal Society of Chemistry 2016
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