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Harnessing NMR relaxation interference effects to characterise supramolecular assemblies.

Abstract:

Solution-state NMR spectroscopy remains the primary method for characterizing synthetic supramolecular assemblies. Yet, in their NMR spectra, relaxation interference effects can significantly alter peak intensities hindering interpretation. Here, we present a simple experiment for synthetic chemists to analyse this effect, allowing interpretion of these distorted spectra and validation of spectral assignments. We apply this experiment to synthetic porphyrin oligomers with molecular weights ap...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted manuscript

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Publisher copy:
10.1039/c6cc02544g

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Department:
Oxford, MPLS, Chemistry, Organic Chemistry
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Author
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Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Engineering and Physical Sciences Research Council More from this funder
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Chemical Communications Journal website
Volume:
52
Issue:
47
Pages:
7450-7453
Publication date:
2016-04-05
Acceptance date:
2016-04-15
DOI:
ISSN:
1364-548X and 1359-7345
Pubs id:
pubs:617739
URN:
uri:1dd7e872-ff50-4e27-bd90-b3bf62600ad9
UUID:
uuid:1dd7e872-ff50-4e27-bd90-b3bf62600ad9
Local pid:
pubs:617739
Language:
English
Keywords:

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