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Harnessing NMR relaxation interference effects to characterise supramolecular assemblies.

Abstract:

Solution-state NMR spectroscopy remains the primary method for characterizing synthetic supramolecular assemblies. Yet, in their NMR spectra, relaxation interference effects can significantly alter peak intensities hindering interpretation. Here, we present a simple experiment for synthetic chemists to analyse this effect, allowing interpretion of these distorted spectra and validation of spectral assignments. We apply this experiment to synthetic porphyrin oligomers with molecular weights ap...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/c6cc02544g

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More from this funder
Name:
Biotechnology and Biological Sciences Research Council
Funding agency for:
Baldwin, A
Grant:
BB/J014346/1
More from this funder
Name:
European Research Council
Funding agency for:
Anderson, H
Grant:
320969
More from this funder
Name:
Engineering and Physical Sciences Research Council
Publisher:
Royal Society of Chemistry
Journal:
Chemical Communications More from this journal
Volume:
52
Issue:
47
Pages:
7450-7453
Publication date:
2016-04-01
Acceptance date:
2016-04-15
DOI:
ISSN:
1364-548X and 1359-7345
Pmid:
27122082
Language:
English
Keywords:
Pubs id:
pubs:617739
UUID:
uuid:1dd7e872-ff50-4e27-bd90-b3bf62600ad9
Local pid:
pubs:617739
Source identifiers:
617739
Deposit date:
2016-12-05

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