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Tantalizing chemistry of the half-sandwich silylhydride complexes of niobium: identification of likely intermediates on the way to agostic complexes.

Abstract:
Reactions of the compound [NbCp(ArN)(PMe3)2] with chlorosilanes HSiRR'Cl give a series of silyl complexes [NbCp(ArN)(PMe3)(H)-(SiRR'Cl)] and [NbCp(ArN)(PMe3)(Cl)(SiRR'H)] which are likely intermediates to the agostic complexes [NbCp(ArN(RR'2Si-H...))-(PMe3)(Cl)].
Publication status:
Published

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Publisher copy:
10.1021/ic026017v

Authors


Nikonov, GI More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Dubberley, SR More by this author
Journal:
Inorganic chemistry
Volume:
42
Issue:
2
Pages:
258-260
Publication date:
2003-01-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:1dc4b185-140a-41bd-b15a-8b62dca014af
Source identifiers:
51211
Local pid:
pubs:51211
Language:
English

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