Journal article
Tantalizing chemistry of the half-sandwich silylhydride complexes of niobium: identification of likely intermediates on the way to agostic complexes.
- Abstract:
- Reactions of the compound [NbCp(ArN)(PMe3)2] with chlorosilanes HSiRR'Cl give a series of silyl complexes [NbCp(ArN)(PMe3)(H)-(SiRR'Cl)] and [NbCp(ArN)(PMe3)(Cl)(SiRR'H)] which are likely intermediates to the agostic complexes [NbCp(ArN(RR'2Si-H...))-(PMe3)(Cl)].
- Publication status:
- Published
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Authors
- Journal:
- Inorganic chemistry More from this journal
- Volume:
- 42
- Issue:
- 2
- Pages:
- 258-260
- Publication date:
- 2003-01-01
- DOI:
- EISSN:
-
1520-510X
- ISSN:
-
0020-1669
- Language:
-
English
- Pubs id:
-
pubs:51211
- UUID:
-
uuid:1dc4b185-140a-41bd-b15a-8b62dca014af
- Local pid:
-
pubs:51211
- Source identifiers:
-
51211
- Deposit date:
-
2012-12-19
Terms of use
- Copyright date:
- 2003
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