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Intrinsic triple order in A-site columnar-ordered quadruple Perovskites: proof of concept

Abstract:

There is an emerging topic in the science of perovskite materials: A-site columnar-ordered A2 A'A''B4 O12 quadruple perovskites, which have an intrinsic triple order at the A sites. However, in many examples reported so far, A' and A'' cations are the same, and the intrinsic triple order is hidden. Here, we investigate structural properties of Dy2 CuMnMn4 O12 (1) and Ho2 MnGaMn4 O12 (2) by neutron and X-ray powder diffraction and prove the triple order at the A sites. The cation distributions...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1002/cphc.201800593

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Role:
Author
ORCID:
0000-0001-9031-2355
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Grant:
JP15K14133
JP16H04501
JSPS Bilateral Open Partnership Joint Research Projects More from this funder
Publisher:
John Wiley and Sons, Inc. Publisher's website
Journal:
ChemPhysChem Journal website
Volume:
19
Issue:
19
Pages:
2449-2452
Publication date:
2018-06-25
Acceptance date:
2018-06-21
DOI:
EISSN:
1439-7641
ISSN:
1439-4235
Pubs id:
pubs:859862
URN:
uri:1da72d17-0d38-4da7-88e5-54ff58bfee42
UUID:
uuid:1da72d17-0d38-4da7-88e5-54ff58bfee42
Local pid:
pubs:859862

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