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6-Azido-3-O-benzyl-6-de-oxy-N,N-diethyl-1,2-O-isopropyl-idene-d-glycero-α-d-gluco-heptofuran-uronamide.

Abstract:

Reaction of 3-O-benzyl-1,2-O-isopropyl-idene-α-xylo-pentodialdo-1,4-furan-ose with N,N-diethyl-2-(dimethyl-sulfuranil-idene)acetamide gave stereoselectively an ep-oxy-amide, which was regioselectively opened by NaN(3) in dimethyl formamide to give the title compound, C(21)H(30)N(4)O(6). X-ray crystallography confirmed the relative stereochemistry of the title compound and the absolute configuration was determined by the use of d-glucose as the starting material. There are two mol-ecules in th...

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Publication status:
Published

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Publisher copy:
10.1107/s1600536810048944

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
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Journal:
Acta crystallographica. Section E, Structure reports online
Volume:
67
Issue:
Pt 1
Pages:
o38-o39
Publication date:
2010-01-01
DOI:
EISSN:
1600-5368
ISSN:
1600-5368
URN:
uuid:1da07f21-caf9-482d-847a-5a495b58f0ff
Source identifiers:
117376
Local pid:
pubs:117376
Language:
English

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