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Synthesis and utility of the 3,3-dimethyl-5-substituted-2-pyrrolidinone Quat' chiral auxiliary

Abstract:
The synthesis and utility of the 3,3-dimethyl-5-substituted-2-pyrrolidinone 'Quat' chiral auxiliary in stereoselective enolate reactions of attached N-acyl side chains combined with the mild and non-racemising conditions required for the ultimate removal of the chiral side chain is described. © 2002 Elsevier Science Ltd. All rights reserved.
Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
TETRAHEDRON-ASYMMETRY More from this journal
Volume:
13
Issue:
6
Pages:
647-658
Publication date:
2002-04-19
DOI:
ISSN:
0957-4166
Language:
English
Pubs id:
pubs:38208
UUID:
uuid:1d8c615f-a8de-462f-be41-3da85de23a84
Local pid:
pubs:38208
Source identifiers:
38208
Deposit date:
2012-12-19

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