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Chloride- and dihydrogenphosphate-selective anion recognition by new acyclic mono-, bis- and tris-cobaltocenium receptors

Abstract:

New acyclic mono-, bis- and tris-cobaltocenium receptors containing aryl, biaryl and pyridine amide moieties have been synthesized and shown from 1H NMR anion-binding studies to exhibit chloride and dihydrogenphosphate anion-selectivity preferences dependent upon the nature of the amide substituent. The single-crystal structure of a chloride complex of one of the receptors has been determined and electrochemical investigations showed that the chloride-selective cobaltocenium derivatives elect...

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Publication status:
Published

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Publisher copy:
10.1039/dt9960004129

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue:
21
Pages:
4129-4134
Publication date:
1996-11-07
DOI:
EISSN:
1364-5447
ISSN:
0300-9246
URN:
uuid:1d5402c6-b93a-434b-a298-506403304597
Source identifiers:
45385
Local pid:
pubs:45385
Language:
English

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