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Simple Analytical Equations for the Current-Potential Curves at Microelectrodes: A Universal Approach

Abstract:

A general, simple, analytical expression for the steady state voltammetric response at electrodes of three different geometries is developed. These geometries have both uniform (isolated microsphere) and nonuniform (microdisc and microsphere supported on an electroinactive surface) accessibility. The expression is applicable over the full range of electrochemical reversibility and for any initial concentrations of both species in the redox couple of interest. By making the assumption that, in...

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Publication status:
Published

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Publisher copy:
10.1021/jp409167m

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
JOURNAL OF PHYSICAL CHEMISTRY C
Volume:
118
Issue:
1
Pages:
346-356
Publication date:
2014-01-09
DOI:
EISSN:
1932-7455
ISSN:
1932-7447
Source identifiers:
448415
UUID:
uuid:1d2b4bb6-f79f-403e-8a1f-297daa31d506
Local pid:
pubs:448415
Deposit date:
2014-06-17

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