Journal article icon

Journal article

Bifunctional iminophosphorane catalyzed enantioselective ketimine phospha-Mannich reaction

Abstract:
The enantioselective phospha-Mannich reaction of diethyl phosphite to unactivated N-DPP-protected ketimines catalyzed by a bifunctional iminophosphorane (BIMP) superbase organocatalyst is described. The reaction is applicable to ketimines bearing electron-rich and electron-poor aryl substituents and occurs with excellent yields and moderate enantioselectivities under mild reaction conditions.
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's Version

Actions


Access Document


Files:
Publisher copy:
10.1055/s-0035-1560530

Authors


Robertson, G More by this author
More by this author
Department:
Wadham College
Publisher:
Thieme Publishing Publisher's website
Journal:
Synlett Journal website
Volume:
27
Issue:
01
Pages:
21-24
Publication date:
2015-12-17
DOI:
EISSN:
1437-2096
ISSN:
0936-5214
Pubs id:
pubs:581183
URN:
uri:1d13c380-9a4d-4c1f-9255-703d3bbf3013
UUID:
uuid:1d13c380-9a4d-4c1f-9255-703d3bbf3013
Local pid:
pubs:581183
Keywords:

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP