Journal article

Bifunctional iminophosphorane catalyzed enantioselective ketimine phospha-Mannich reaction

Abstract:: The enantioselective phospha-Mannich reaction of diethyl phosphite to unactivated N-DPP-protected ketimines catalyzed by a bifunctional iminophosphorane (BIMP) superbase organocatalyst is described. The reaction is applicable to ketimines bearing electron-rich and electron-poor aryl substituents and occurs with excellent yields and moderate enantioselectivities under mild reaction conditions.

Publication status:: Published

Peer review status:: Peer reviewed

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APA Style

Robertson, G., Farley, A., & Dixon, D. (2015). Bifunctional iminophosphorane catalyzed enantioselective ketimine phospha-Mannich reaction. Synlett, 27(01), 21–24.

MLA Style

Robertson, G., et al. “Bifunctional Iminophosphorane Catalyzed Enantioselective Ketimine Phospha-Mannich Reaction.” Synlett, vol. 27, no. 01, Thieme Publishing, 2015, pp. 21–24.

Chicago Style

Robertson, G, A Farley, and D Dixon. 2015. “Bifunctional Iminophosphorane Catalyzed Enantioselective Ketimine Phospha-Mannich Reaction.” Synlett 27 (01): 21–24.
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Files:: DJD BIMP phosphaMannich Manuscript final.pdf

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Publisher copy:: 10.1055/s-0035-1560530

Authors

+ Robertson, G More by this author

Role:: Author

+ Farley, A More by this author

Role:: Author

+ Dixon, D More by this author

Institution:: University of Oxford
Oxford college:: Wadham College
Role:: Author

Publisher:: Thieme Publishing
Journal:: Synlett More from this journal
Volume:: 27
Issue:: 01
Pages:: 21-24
Publication date:: 2015-12-17
Acceptance date:: 2015-10-24
DOI:: 10.1055/s-0035-1560530
EISSN:: 1437-2096
ISSN:: 0936-5214

Keywords:: SBTMR
Pubs id:: pubs:581183
UUID:: uuid:1d13c380-9a4d-4c1f-9255-703d3bbf3013
Local pid:: pubs:581183
Source identifiers:: 581183
Deposit date:: 2016-12-02

Terms of use

Copyright holder:: Georg Thieme Verlag
Copyright date:: 2015
Notes:: © Georg Thieme Verlag Stuttgart · New York

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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