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Metal-driven ligand assembly in the synthesis of cyclodextrin [2] and [3]rotaxanes.

Abstract:

Cyclodextrin [2] and [3]rotaxanes have been synthesised by use of a metal-driven ligand formation methodology. The kinetically stable cobalt(III) complexes formed act as either linking or capping groups, the function being selected by manipulation of the reaction conditions to promote the formation of either 2:1 or 1:1 complexes, respectively. In all cases, mixtures of isomers containing different alpha-cyclodextrin orientations were observed. All three orientational isomers of the [3]rotaxan...

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Publication status:
Published

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Publisher copy:
10.1039/b616621k

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
Organic and biomolecular chemistry
Volume:
5
Issue:
3
Pages:
457-462
Publication date:
2007-02-01
DOI:
EISSN:
1477-0539
ISSN:
1477-0520
Language:
English
Pubs id:
pubs:51764
UUID:
uuid:1a8ed509-a09a-41b4-8653-8bffd9694b15
Local pid:
pubs:51764
Source identifiers:
51764
Deposit date:
2012-12-19

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