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Probing the structure, dynamics, and bonding of coinage metal complexes of white phosphorus

Abstract:

A series of cationic white phosphorus complexes of the coinage metals Au and Cu have been synthesised and characterised both in the solid state and in solution. All complexes feature a P4 unit coordinated through an edge P-P vector (η(2)-like), although the degree of activation (as measured by the coordinated P-P bond length) is greater in the gold species. All of the cations are fluxional on the NMR timescale at room temperature, but in the case of the gold systems fluxionality is frozen out...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1002/chem.201505031

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
University of Bristol More from this funder
European Union More from this funder
COST Action More from this funder
Publisher:
Wiley Online Library Publisher's website
Journal:
Chemistry - A European Journal Journal website
Volume:
22
Issue:
15
Pages:
5397–5403
Publication date:
2016-02-25
DOI:
ISSN:
0947-6539 and 1521-3765
Pubs id:
pubs:609507
URN:
uri:19248e74-911e-4c98-882e-db9be0ddacb3
UUID:
uuid:19248e74-911e-4c98-882e-db9be0ddacb3
Local pid:
pubs:609507
Paper number:
15

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