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Linear sweep voltammetry with non-triangular waveforms at a microdisc electrode

Abstract:

The voltammetry of an electrochemically reversible reaction at a microdisc electrode is investigated for a semi-circular potential waveform. At the midpoint of the potential window an instantaneous infinite scan rate is observed while relatively slow scan rates are seen in other areas of the wave. As a result, the method exhibits a much higher current response than the conventional triangular potential wave thus allowing qualitative analysis of a species with significantly greater ease, parti...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1016/j.jelechem.2018.06.049

Authors


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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Oxford college:
Keble College
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Subgroup:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Subgroup:
Physical & Theoretical Chem
Oxford college:
St Johns College
Role:
Author
ORCID:
0000-0001-9841-5041
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Grant:
Seventh Framework Programme, FP/2007-2013; 320403
Publisher:
Elsevier Publisher's website
Journal:
Journal of Electroanalytical Chemistry Journal website
Volume:
823
Pages:
465-473
Publication date:
2018-06-30
Acceptance date:
2018-06-27
DOI:
EISSN:
1873-2569
ISSN:
1572-6657
Pubs id:
pubs:891105
URN:
uri:17a40609-a142-417e-a4cd-cfab3559348f
UUID:
uuid:17a40609-a142-417e-a4cd-cfab3559348f
Local pid:
pubs:891105

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