Journal article icon

Journal article

Titanium imido complexes of cyclooctatetraenyl ligands.

Abstract:

Reaction of [Ti(NR)Cl2(py)3] (R=tBu or 2,6-iPr2C6H3) with K(2)[COT] (COT=C8H8) or Li2[COT''] (COT''=1,4-C8H6(SiMe3)2) gave the monomeric complexes [Ti(NR)(eta8-COT)] or [Ti(NR)(eta8-COT'')], respectively. The pseudo-two coordinate, "pogo stick" geometry for these complexes is unique in both early transition-metal and cyclooctatetraenyl ligand chemistry. In contrast, reaction of [Ti(N-2,6-Me2C6H3)Cl2(py)3] with K2[COT] gave the mu-imido-bridged dimer [Ti2(mu-N-2,6-Me2C6H3)2(eta8-COT)2]. It app...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1002/chem.200401104

Authors


Expand authors...
Journal:
Chemistry (Weinheim an der Bergstrasse, Germany)
Volume:
11
Issue:
7
Pages:
2111-2124
Publication date:
2005-03-05
DOI:
EISSN:
1521-3765
ISSN:
0947-6539
URN:
uuid:17a30366-1169-406e-a2f3-11d3545daa54
Source identifiers:
32998
Local pid:
pubs:32998

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP