Journal article icon

Journal article

A generic one-pot route to acyclic two-coordinate silylenes from silicon(IV) precursors: synthesis and structural characterization of a silylsilylene.

Abstract:
Si in sight: a one-pot, single-step synthesis of an acyclic silylsilylene, Si{Si(SiMe(3))(3)}{N(SiMe(3))Dipp} (Dipp=2,6-iPr(2)C(6)H(3)), from a silicon(IV) starting material is reported, together with evidence for a mechanism involving alkali metal silylenoid intermediates.
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1002/anie.201208554

Authors


Expand authors...
Journal:
Angewandte Chemie (International ed. in English)
Volume:
52
Issue:
2
Pages:
568-571
Publication date:
2013-01-05
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:178c4bf3-75c8-4b24-a7e0-40cb1e620f8e
Source identifiers:
363795
Local pid:
pubs:363795
Language:
English
Keywords:

Terms of use


Metrics


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP