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Magnetic properties of CeMn2-xCoxGe4O12 (0 ≤ x ≤ 2) as a function of temperature and magnetic field

Abstract:

Polycrystalline samples, prepared by a solid-state route, of compositions in the solid solution CeMn2-xCoxGe4O12 (x = 0.0, 0.5, 1.0, 1.5, and 2.0) were characterized by X-ray diffraction, neutron diffraction, and magnetometry. They adopt space group P4/nbm with a ≈ 9.78 and c ≈ 4.85 Å and become anti-ferromagnetic (x = 0.0, 1.5, 2.0) or weakly ferromagnetic (x = 0.5, 1.0) at 4.2 ≤ T ≤ 7.6 K. The ordered moments lie along [001] when x = 0.0 and in the (001) plane otherwise. The unit cell doubl...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1021/acs.inorgchem.6b02905

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Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
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Department:
St Catherines College
Publisher:
American Chemical Society Publisher's website
Journal:
Inorganic Chemistry Journal website
Volume:
56
Issue:
5
Pages:
2750–2762
Publication date:
2017-02-15
Acceptance date:
2017-01-31
DOI:
ISSN:
1520-510X
Pubs id:
pubs:681691
URN:
uri:14eea71b-e692-4d28-b270-def7c0e31c11
UUID:
uuid:14eea71b-e692-4d28-b270-def7c0e31c11
Local pid:
pubs:681691
Language:
English

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