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Scavenger templates: a systems chemistry approach to the synthesis of porphyrin-based molecular wires

Abstract:
A hexa-pyridyl template can be used as a scavenger to facilitate the synthesis of a linear porphyrin dodecamer from a mixture of linear hexamers with one or two terminal reactive groups. The template suppresses polymer formation by rapidly cyclizing the fully deprotected hexamer, thus upregulating formation of the linear dodecamer.
Publication status:
Published
Peer review status:
Peer reviewed

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Files:
Publisher copy:
10.1039/c7cc04289b

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author


Publisher:
Royal Society of Chemistry
Journal:
Chemical Communications More from this journal
Volume:
53
Issue:
75
Pages:
10410-10413
Publication date:
2017-09-07
Acceptance date:
2017-08-29
DOI:
ISSN:
0009-241X


Pubs id:
pubs:725015
UUID:
uuid:1495420d-8a22-4f87-858c-03e47f83b3fd
Local pid:
pubs:725015
Source identifiers:
725015
Deposit date:
2017-09-02

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