Site-selective traceless Staudinger ligation for glycoprotein synthesis reveals scope and limitations.
- Making it traceless: A traceless Staudinger reaction between a specifically functionalized sugar phosphine and an azide-tagged protein allows the construction of well-defined reverse N-linked glycoproteins (see scheme). This reaction was applied to different azidoprotein substrates and its potentials and limitations are outlined. © 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
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- Chembiochem : a European journal of chemical biology
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