- Abstract:
- The shape and nature of the chronoamperometric transients resulting from double-potential steps at rotating-disc electrodes, when the electrode reaction is of the ECE or DISP1 type, have been considered. It has been shown that such measurements can provide a clear discrimination between these two mechanistic pathways and this conclusion is verified in respect of the reduction of fluorescein in the pH range 9-10, which is shown to involve a DISP1 mechanism, in agreement with other observations.
- Publication status:
- Published
- Publisher copy:
- 10.1039/f19888402057
-
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- Journal:
- JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I
- Volume:
- 84
- Issue:
- 6
- Pages:
- 2057-2068
- Publication date:
- 1988
- DOI:
- ISSN:
-
0300-9599
- URN:
-
uuid:12566e94-22ac-4882-a9de-ee05a9a4dcf3
- Source identifiers:
-
42887
- Local pid:
- pubs:42887
- Language:
- English
- Copyright date:
- 1988
Journal article
ROTATING-DISK ELECTRODES - SINGLE-POTENTIAL AND DOUBLE-POTENTIAL STEP CHRONOAMPEROMETRY AND THE ECE-DISP1 PROBLEM
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