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Journal article

Spin-forbidden dissociation of ozone in the Huggins bands

Abstract:

Dissociation of ozone close to room temperature in the Huggins bands between 310 and 328 nm has been studied by time-of-flight spectroscopy of the resultant O(1D) and O2(a 1Δg) fragments. Clear evidence is seen for the spin-forbidden formation of both of these products in conjunction with the triplet (ground) state co-fragment, as well as for the dissociation of internally excited ozone molecules to form both singlet products in a spin-allowed step. For O(1D) the ratio of spin-forbidden to sp...

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Publication status:
Published

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
CHEMICAL PHYSICS
Volume:
231
Issue:
2-3
Pages:
109-119
Publication date:
1998-06-01
DOI:
ISSN:
0301-0104
Language:
English
Pubs id:
pubs:36567
UUID:
uuid:11fb8664-95b4-41b7-9be1-cde8fb536f83
Local pid:
pubs:36567
Source identifiers:
36567
Deposit date:
2012-12-19

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