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On the charge density refinement of odd-order multipoles invariant under crystal point group symmetry

Abstract:

Charge density studies utilise a multipolar expansion of the atomic density (and the associated atomic scattering factor) in order to model asphericity. Contributions of the individual multipoles to the atomic density are then refined as multipole population coefficients. Refinement of these coefficients pertaining to odd-order multipoles that are invariant under the crystal point-group symmetry is often problematic, with ill-defined values and correlations plaguing the convergence to a good ...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.3390/sym9050063

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Institution:
University of Oxford
Division:
MSD
Department:
Biochemistry
Role:
Author
Publisher:
MDPI Publisher's website
Journal:
Symmetry Journal website
Volume:
9
Issue:
5
Pages:
1-8
Publication date:
2017-04-26
Acceptance date:
2017-04-21
DOI:
ISSN:
2073-8994
Keywords:
Pubs id:
pubs:719052
UUID:
uuid:0b9b38c5-3cfa-4143-848a-9e996d48abea
Local pid:
pubs:719052
Source identifiers:
719052
Deposit date:
2017-11-13

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