Journal article
Monometallic and bimetallic titanium κ1‑amidinate complexes as olefin polymerization catalysts
- Abstract:
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A series of cyclopentadienyl-κ1-amidinate titanium complexes Cp*Ti{NC(ArR)NiPr2}Me2 (ArR = 4-C6H4R, where R = H (1-Me), CF3 (5-Me), tBu (6-Me), or NMe2 (7-Me)) with different para-substituents in the amidinate ligand were synthesized and structurally characterized, along with three bimetallic analogues: 1,4-C6H4{C(NiPr2)N}2{Cp*TiMe2}2 (2-Me), 1,3-C6H4{C(NiPr2)N}2{Cp*TiMe2}2 (3-Me), and CH2{1,4-C6H4-C(NiPr2)N}2{Cp*TiMe2}2 (4-Me). 13C NMR spectroscopy, density function theory, and the quantum t...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
-
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(Accepted manuscript, pdf, 725.9KB)
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- Publisher copy:
- 10.1021/acs.organomet.7b00225
Authors
Funding
Arlanxeo Netherlands B.V.
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Bibliographic Details
- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Organometallics Journal website
- Volume:
- 36
- Issue:
- 11
- Pages:
- 2167-2181
- Publication date:
- 2017-05-30
- Acceptance date:
- 2017-05-15
- DOI:
- EISSN:
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1520-6041
- ISSN:
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0276-7333
Item Description
- Pubs id:
-
pubs:700456
- UUID:
-
uuid:0a1c4446-e676-49b9-8a8e-c524af4eab6b
- Local pid:
- pubs:700456
- Source identifiers:
-
700456
- Deposit date:
- 2017-06-14
Terms of use
- Copyright holder:
- © 2017 American Chemical Society
- Copyright date:
- 2017
- Notes:
- This is the author accepted manuscript following peer review version of the article. The final version is available online from American Chemical Society at: 10.1021/acs.organomet.7b00225
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