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The partial dehydrogenation of aluminium dihydrides

Abstract:

The reactions of a series of b-diketiminate stabilised aluminium dihydrides with ruthenium bis(phosphine), palladium bis(phosphine) and palladium cyclopentadienyl complexes is reported. In the case of ruthenium, alane coordination occurs with no evidence for hydrogen loss resulting in the formation of ruthenium complexes with a pseudo-octahedral geometry and cis-relation of phosphine ligands. These new ruthenium complexes have been characterised by multinuclear and variable temperature NMR sp...

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Publication status:
Published
Peer review status:
Peer reviewed

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Files:
Publisher copy:
10.1039/c9sc02750e

Authors


Publisher:
Royal Society of Chemistry
Journal:
Chemical Science More from this journal
Volume:
10
Issue:
35
Pages:
8049-8274
Publication date:
2019-08-13
Acceptance date:
2019-08-12
DOI:
EISSN:
2041-6539
ISSN:
2041-6520
Language:
English
Pubs id:
pubs:1043363
UUID:
uuid:090e5c87-ae6d-4cc5-9b6c-448219b31ef5
Local pid:
pubs:1043363
Source identifiers:
1043363
Deposit date:
2019-08-13

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