Journal article icon

Journal article

Modulation of σ-alkane interactions in [Rh(L2)(alkane)]+ Solid-State Molecular Organometallic (SMOM) systems by variation of the chelating phosphine and alkane: Access to η2,η2-σ-alkane Rh(I), η1-σ-alkane Rh(III) complexes, and alkane encapsulation

Abstract:

Solid/gas Single–Crystal to Single–Crystal (SC–SC) hydrogenation of appropriate diene precursors forms the corresponding σ–alkane complexes [Rh(Cy2P(CH2)nPCy2)(L)][BArF4] (n = 3, 4) and [RhH(Cy2P(CH2)2(CH)(CH2)2PCy2)(L)][BArF4] (n = 5, L = norbornane, NBA; cyclooctane, COA). Their struc-tures, as determined by single–crystal X-ray diffraction, have cations exhibiting Rh···H–C σ–interactions which are modulated by both the chelating ligand and the identity of the alkane, while all sit in an oc...

Expand abstract
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's Version

Actions


Access Document


Files:
Publisher copy:
10.1021/jacs.8b09364

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Role:
Author
Expand authors...
Publisher:
American Chemical Society Publisher's website
Journal:
Journal of the American Chemical Society Journal website
Volume:
140
Issue:
44
Pages:
14958–14970
Publication date:
2018-10-10
Acceptance date:
2018-10-10
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Pubs id:
pubs:926254
URN:
uri:08446863-b3c4-46cb-9886-a63b2fc438bf
UUID:
uuid:08446863-b3c4-46cb-9886-a63b2fc438bf
Local pid:
pubs:926254

Terms of use


Metrics


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP