- Abstract:
-
Solid/gas Single–Crystal to Single–Crystal (SC–SC) hydrogenation of appropriate diene precursors forms the corresponding σ–alkane complexes [Rh(Cy2P(CH2)nPCy2)(L)][BArF4] (n = 3, 4) and [RhH(Cy2P(CH2)2(CH)(CH2)2PCy2)(L)][BArF4] (n = 5, L = norbornane, NBA; cyclooctane, COA). Their struc-tures, as determined by single–crystal X-ray diffraction, have cations exhibiting Rh···H–C σ–interactions which are modulated by both the chelating ligand and the identity of the alkane, while all sit in an oc...
Expand abstract - Publication status:
- Published
- Peer review status:
- Peer reviewed
- Version:
- Publisher's Version
- Files:
-
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(pdf, 7.3MB)
-
- Publisher copy:
- 10.1021/jacs.8b09364
-
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- Publisher:
- American Chemical Society Publisher's website
- Journal:
- Journal of the American Chemical Society Journal website
- Volume:
- 140
- Issue:
- 44
- Pages:
- 14958–14970
- Publication date:
- 2018-10-10
- Acceptance date:
- 2018-10-10
- DOI:
- EISSN:
-
1520-5126
- ISSN:
-
0002-7863
- Pubs id:
-
pubs:926254
- URN:
-
uri:08446863-b3c4-46cb-9886-a63b2fc438bf
- UUID:
-
uuid:08446863-b3c4-46cb-9886-a63b2fc438bf
- Local pid:
- pubs:926254
- Copyright holder:
- American Chemical Society
- Copyright date:
- 2018
- Notes:
- © 2018 American Chemical Society. ACS AuthorChoice - This is an open access article published under a Creative Commons Attribution (CC-BY) License, which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
Journal article
Modulation of σ-alkane interactions in [Rh(L2)(alkane)]+ Solid-State Molecular Organometallic (SMOM) systems by variation of the chelating phosphine and alkane: Access to η2,η2-σ-alkane Rh(I), η1-σ-alkane Rh(III) complexes, and alkane encapsulation
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