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Structural and magnetic conformation of a cerocene [Ce(COT′′)2]− exhibiting a uniconfigurational f1 ground state and slow-magnetic relaxation

Abstract:
Magnet-like behaviour, in the form of slow relaxation of the magnetization, was observed for a monometallic cerium(III) sandwich complex. The use of trimethylsilyl substituted COT ligands (COT′′) led to the formation of a staggered COT′′ arrangement in the cerocene-type sandwich complex with a well-defined oxidation state of +3 for the Ce ion.
Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1039/C3DT53280A

Authors


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Department:
Oxford, MPLS, Materials
Korobkov, I More by this author
Schelter, EJ More by this author
Murugesu, M More by this author
Publisher:
Royal Society of Chemistry Publisher's website
Journal:
Dalton Transactions Journal website
Volume:
43
Issue:
7
Pages:
2737–2740
Publication date:
2013-12-11
Acceptance date:
2013-12-11
DOI:
ISSN:
1477-9234 and 1477-9226
Pubs id:
pubs:652760
URN:
uri:05ca1206-5412-4b5c-85ef-111fce0e2366
UUID:
uuid:05ca1206-5412-4b5c-85ef-111fce0e2366
Local pid:
pubs:652760
Keywords:

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