- Abstract:
- Magnet-like behaviour, in the form of slow relaxation of the magnetization, was observed for a monometallic cerium(III) sandwich complex. The use of trimethylsilyl substituted COT ligands (COT′′) led to the formation of a staggered COT′′ arrangement in the cerocene-type sandwich complex with a well-defined oxidation state of +3 for the Ce ion.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
- Publisher copy:
- 10.1039/C3DT53280A
-
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- Publisher:
- Royal Society of Chemistry Publisher's website
- Journal:
- Dalton Transactions Journal website
- Volume:
- 43
- Issue:
- 7
- Pages:
- 2737–2740
- Publication date:
- 2013-12-11
- Acceptance date:
- 2013-12-11
- DOI:
- ISSN:
-
1477-9234 and 1477-9226
- Pubs id:
-
pubs:652760
- URN:
-
uri:05ca1206-5412-4b5c-85ef-111fce0e2366
- UUID:
-
uuid:05ca1206-5412-4b5c-85ef-111fce0e2366
- Local pid:
- pubs:652760
- Keywords:
- Copyright holder:
- The Royal Society of Chemistry
- Copyright date:
- 2013
Journal article
Structural and magnetic conformation of a cerocene [Ce(COT′′)2]− exhibiting a uniconfigurational f1 ground state and slow-magnetic relaxation
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