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Particle Size and Surface Coverage Effects in the Stripping Voltammetry of Silver Nanoparticles: Theory and Experiment

Abstract:

Theory is presented for a mathematical model that includes two-dimensional diffusion for the stripping of randomly distributed metal nanoparticles. Theoretical results are compared with the reversible and irreversible limits in the approximate analytical form derived by Brainina and co-workers (Brainina, K. Z. Talanta 1971, 18, 513. Brainina, K. Z.; Lesunova, R. P. Zh. Anal. Khim. 1974, 29, 1302. Brainina, K. Z.; Vydrevich, M. B. J. Electroanal. Chem. 1981, 121, 1.) when considering an averag...

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Publication status:
Published

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Publisher copy:
10.1021/jp807093q

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
JOURNAL OF PHYSICAL CHEMISTRY C
Volume:
112
Issue:
46
Pages:
17820-17827
Publication date:
2008-11-20
DOI:
EISSN:
1932-7455
ISSN:
1932-7447
Source identifiers:
40964
Language:
English
UUID:
uuid:03f19f29-6556-4ded-bcb7-dd7cb164c862
Local pid:
pubs:40964
Deposit date:
2012-12-19

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