Journal article

Substitution chemistry of sterically demanding boryl ligands

Abstract:: The synthetic and reaction chemistry of the asymmetric aryl(bromo)boryl complexes (η5- C5H5)Fe(CO)2B(Ar)Br [Ar = 2,4,6-Me3C6H2, Mes (3); 2,6-(2,4,6-iPr3C6H2) C6H3, 2,6-Trip2C6H3 (4)] are reported. In particular, the scope for substitution at boron by main-group nucleophiles is probed. The synthesis and characterization of (η5-C5H5)Fe(CO)2B(Mes) ERn [ERn = OtBu, (5); ERn = SPh (6)] confirm that substitution at boron can be accomplished with retention of the Fe-B bond. Copyright © 2003 John Wiley and Sons, Ltd.

Publication status:: Published

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APA Style

Coombs, D., Aldridge, S., & Jones, C. (2003). Substitution chemistry of sterically demanding boryl ligands. APPLIED ORGANOMETALLIC CHEMISTRY, 17(6-7), 356–360.

MLA Style

Coombs, D, et al. “Substitution Chemistry of Sterically Demanding Boryl Ligands.” APPLIED ORGANOMETALLIC CHEMISTRY, vol. 17, nos. 6-7, 2003, pp. 356–60.

Chicago Style

Coombs, D, S Aldridge, and C Jones. 2003. “Substitution Chemistry of Sterically Demanding Boryl Ligands.” APPLIED ORGANOMETALLIC CHEMISTRY 17 (6-7): 356–60.
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Publisher copy:: 10.1002/aoc.426

Authors

+ Coombs, D More by this author

Role:: Author

+ Aldridge, S More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Jones, C More by this author

Role:: Author

Journal:: APPLIED ORGANOMETALLIC CHEMISTRY More from this journal
Volume:: 17
Issue:: 6-7
Pages:: 356-360
Publication date:: 2003-01-01
DOI:: 10.1002/aoc.426
EISSN:: 1099-0739
ISSN:: 0268-2605

Language:: English
Keywords:: substitution

boryl

boron

iron

cyclopentadienyl
Pubs id:: pubs:46063
UUID:: uuid:01d309f6-8b62-4844-bfed-01d960bb5b0b
Local pid:: pubs:46063
Source identifiers:: 46063
Deposit date:: 2012-12-19
ARK identifier:: ark:/29072/ora_01d309f68b624844bfed01d960bb5b0b

Terms of use

Copyright date:: 2003

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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