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Time-resolved dissociation of the H-2-OH entrance channel complex

Abstract:
Time-resolved experiments and calculations are reported for the predissociation dynamics of the metastable vOH=2 vibrational state of H2-OH and D2-OH in their ground electronic states. Good agreement between theory and experiment is found for the absolute lifetimes of H2-OH and relative product state distributions for D2-OH. The excited vibrational state lifetimes are 10-9 and 10-6 s for the complexes containing D2 and H2, respectively.
Publication status:
Published

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Authors


Krause, PJ More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Anderson, DT More by this author
Schwartz, RL More by this author
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Journal:
CHEMICAL PHYSICS LETTERS
Volume:
294
Issue:
6
Pages:
518-522
Publication date:
1998-09-25
DOI:
ISSN:
0009-2614
URN:
uuid:01851c43-44b7-476f-8891-14d40ba56f33
Source identifiers:
52794
Local pid:
pubs:52794
Language:
English

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